Baez, ranked No 31, will play the winner of the match between Argentinian lucky loser Camilo Ugo Carabelli and Portuguese lucky loser Jaime Faria next.
The Argentinian won against lucky loser Roman Andres Burruchaga (6-3, 7-5) and Mariano Navone (6-4, 1-6, 6-3) ahead of his victory.
Earlier in the tournament, Tseng, ranked No 125, beat Chilean Alejandro Tabilo, the No 3 seed (6-2, 7-5) and edged out Brazilian wildcard Thiago Monteiro (6-7 (4), 6-3, 7-6 (4)).
Rio de Janeiro ATP 500, other last 8 results (Jockey Club Brasileiro, clay, USD 2.396.115, most recent results first):
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